RoHS is a guideline regarding the regulated usage of six types of toxic substances (Pb, Cd, Cr6+, Hg, PBB, PBDE), and Pb Free is a regulation only for Pb.
In other words, RoHS can be said to include Pb Free. The Pb Free regulation has been in effective since a few years ago, and RoHS has been in effect in the EU since July 1, 2006. If you satisfy RoHS, then you will certainly satisfy Pb Free.